Does it work well for leather boots?

I wouldn't use in on leather, I use Dainese leather care on my boots, This product work well on my textile jacket.

Will this help elevate the musty smell in my walking boots ,taken out the insoles but boots still smell.

This product will help alleviate musty smells in shoes and walking boots, as will any cleaning action removing dirt, some of the oils and fats causing the odors and removing some bacteria. But if you want to really want to focus on removing odor we would recommend Grangeres Odor Eliminator. this product as the name sugests is specifically designed to reduce and remove odors in footwear.

Color	Transparent
Size	275 ml (Pack of 1)
Style	Gear Cleaner
Height	6 inches
Item display length	6 inches
Weight	264 g
Item display width	1 inches
Material type	Plastic Bottles
Number of items	1
Number of pieces	1
Seasons	Year-round
Features	Cleans gear and removes odours without affecting the DWR found on most technical gear
Usage	hiking
Sport	Camping & Hiking
Batteries included?	No
Brand	Granger's
Department	Unisex
Manufacturer	Grangers International
Item model number	GRF77
Product Dimensions	22 x 8.99 x 22 cm; 261.72 g
ASIN	B00R1FOABW

Granger's

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